منابع مشابه
Niobium Pentachloride Catalysed Ring Opening of Epoxides
Epoxide ring opening is a frequently required transformation in Organic Synthesis. In this paper we describe the application of NbCl5 for this purpose using three different substrates. Chlorohydrins, 1,2-diols, products containing solvent residues as well as rearrangement products are obtained, depending on both the substrate structure and reaction conditions. Rationalizations to account for so...
متن کاملAntimony Toxicity
Antimony toxicity occurs either due to occupational exposure or during therapy. Occupational exposure may cause respiratory irritation, pneumoconiosis, antimony spots on the skin and gastrointestinal symptoms. In addition antimony trioxide is possibly carcinogenic to humans. Improvements in working conditions have remarkably decreased the incidence of antimony toxicity in the workplace. As a th...
متن کاملThe interaction of molybdenum pentachloride with O- and S-heterocycles.
The 1 : 2 molar reactions of MoCl5, in dichloromethane at room temperature, with tetrahydrofuran (thf), tetrahydropyran (thp), dioxane and tetrahydrothiophene (tht) afforded, respectively, [Mo(O)Cl3(thf)]2, 1, and MoCl4(L)2 (L = thp, 2; dioxane, 3; tht, 4), in 81-87% yields. The molecular structures of 1, 2 and 4 were ascertained by X-ray diffractometry. DFT and spectroscopic (IR, NMR) studies ...
متن کاملDisintegration of antimony-124.
The radiations from 60-day Sb lN have been studied by several investigators. H ales and Jordan [2] used a 1800 spectrometer to study the beta spectrum of Sb124. Tbey report the presence of two components with maximum cnergies at 0.74 ± O.03 and 2.45 ± 0.07 million electron volts (NIev) . ~1iller and Omtiss [3], u ing a thin magnetic len spectrometer , also ob erved a complex beta specLrum, but ...
متن کامل34 Antimony-resistant.pmd
1Institute of Endemic Diseases, University of Khartoum, Khartoum, Sudan. ABSTRACT A longitudinal study was done in a leishmaniasis-endemic region in eastern Sudan during the period November 2001–February 2003 to determine the incidence of failure of sodium stibogluconate treatment. We studied 820 confirmed visceral leishmaniasis patients. All were treated with sodium stibogluconate, 20 mg/kg bo...
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ژورنال
عنوان ژورنال: Synlett
سال: 2005
ISSN: 0936-5214,1437-2096
DOI: 10.1055/s-2005-868486